Téléchargez le livre : Enantioselective Electrochemical C–H Activation Enabled by Sustainable 3d Transition Metal Catalysis

Enantioselective Electrochemical C–H Activation Enabled by Sustainable 3d Transition Metal Catalysis

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Springer Spektrum


Paru le : 2025-02-20

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Description

Enantioselective metallaelectro-catalyzed C-H activation represents an innovative strategy for enabling the transition of organic synthesis to a more resource-economic mode of operation. It circumvents substrate prefunctionalization by directly exploiting otherwise inert C-H bonds to construct complex three-dimensional scaffolds from simple molecular building blocks. Furthermore, the mild electrocatalytic conditions evade chemical oxidants, while producing molecular hydrogen as the sole by-product, enabling the connection of organic synthesis to a possible future decentralized green hydrogen economy.
Still, disclosed methodologies predominantly rely on noble metal catalysts. Examples using earth-abundant 3d transition metals remain scarce despite the substantially improved ecological and economic implications and diminished toxicity. This work addresses this shortcoming by investigating the first enantioselective nickelaelectro-catalyzed C-H activation and various cobaltaelectro-catalyzed conversions. On this occasion, the synthetic versatility is examined and various mechanistic experiments are presented for fostering future developments.
Pages
96 pages
Collection
n.c
Parution
2025-02-20
Marque
Springer Spektrum
EAN papier
9783658471095
EAN PDF
9783658471101
Informations sur l'ebook
Nombre pages copiables
0
Nombre pages imprimables
9
Taille du fichier
5110 Ko
Prix
94,94 €
EAN EPUB
9783658471101
Informations sur l'ebook
Nombre pages copiables
0
Nombre pages imprimables
9
Taille du fichier
13496 Ko
Prix
94,94 €

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